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Hydrobromic acid
   
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Hydrobromic acid
Hydrobromic acid
Identifiers
CAS number [10035-10-6]
RTECS number MW3850000
Properties
Molecular formula HBr
Molar mass 80.91 g/mol
Appearance colorless liquid
Density variable
Melting point

variable

Boiling point

variable

Solubility in water aqueous solution
Acidity (pKa) -9
Hazards
EU classification Corrosive (C)
NFPA 704
0
3
0
 
R-phrases R34, R37
S-phrases (S1/2), S7/9, S26, S45
Flash point non flammable
Related compounds
Other anions Fluoride
Chloride
Iodide
Related compounds Hydrogen bromide
Except where noted otherwise, data are given for
materials in their standard state
(at 25 °C, 100 kPa)

Infobox references

Hydrobromic Acid is a strong acid formed by dissolving the diatomic molecule hydrogen bromide in water. It has a pKa of -9, making it a stronger acid than hydrochloric acid, but not as strong as hydroiodic acid. Hydrobromic acid is one of the strongest mineral acids known.

Contents

Uses

Hydrobromic acid is mainly used for the production of inorganic bromides, cleaning alkoxy and phenoxy compounds, substitution of hydroxyl groups, and the hydrobromination of alkenes. It also catalyzes alkylation reactions and the extraction of certain ores.[1]

Syntheses

Hydrobromic acid can be prepared in the laboratory via the reaction of Br2, SO2, and water.[2] More typically laboratory preparations involve the production of anhydrous HBr, which is then dissolved in water.

Hydrobromic acid has commonly been prepared industrially by reacting bromine with either sulfur or phosphorus and water. However, it can also be produced electrolytically.[2]. It can also be prepared by treating bromides with non-oxidising acids like phosphoric or acetic acids.

Hydrobromic acid is available in various concentrations and purities.

References

  1. ^ Carlin, W. W. U.S. Patent 4,147,601 
  2. ^ a b Scott, A. (1900). "Preparation of pure hydrobromic acid". J. Chem. Soc., Trans. 77: 648–650. doi:10.1039/ct9007700648. 

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